太湖五里湖背角无齿蚌体内滴滴涕和六六六的残留

    DDT and HCH Residues in Anodonta woodiana in Wuli Lake of the Taihu Lake

    • 摘要: 作为建立淡水“贝类观察”体系的初步尝试,选定2003年3月采自太湖五里湖水域的背角无齿蚌(Anodonta woodiana)为研究对象,测定其体内滴滴涕(DDT)和六六六(HCH)含量。除β型外,α型、γ型和δ型HCH异构体及p,p’-DDE,o,p’-DDT,p,p’-DDD,p,p’-DDT均在蚌样本中明显检出。∑DDTs湿重含量5.86~14.13 ng.g-1平均(9.27±3.04)ng.g-1,高于∑HCHs湿重含量2.45~6.46 ng.g-1平均(4.00±1.22)ng.g-1p,p′-DDE、p,p'-DDD与α型、γ型HCH异构体分别为∑DDTs和∑HCHs的优势组分,说明太湖五里湖水域目前DDT的污染源可能很少,但存在较明显的新输入HCH。各蚌样的残留水平没有超过农业部、美国食品与药品管理局(FDA)和联合国粮农组织(FAO)颁布的最大限量。

       

      Abstract: As an initial attempt to set up a "Freshwater Mussel Watching" system,swan mussels(Anodonta woodiana) were collected from Wuli Lake of the Taihu Lake in March 2003 for analysis by gas chromatography of dichlorodiphenyltrichloroethanes(DDT)(p,p′-DDE,o,p′-DDT,p,p′-DDD,p,p′-DDT),and α-,β-,γ-,δ-hexachlorocyclohexane (HCH) isomers in soft tissues.Except for β-HCH isomer,all DDT and HCH isomers were detected in these mussels.ΣDDTs concentration range: 5.86~14.13 ng·g-1 wet weight,mean±S.D.:(9.27±3.04) ng·g-1 wet weight,n=10 were higher than ΣHCHs concentration range: 2.45~6.46 ng·g-1 wet weight,mean±S.D.:(4.00±1.22) ng·g-1 wet weight,n=10.The former was dominated with p,p′-DDE,p,p′-DDD,while the latter with α-,γ-HCH,suggesting that recently input of DDT was getting little, but the input of HCH was apparent in the region.However,DDT and HCH residues in the mussel samples were still lower than the threshold values set by the Ministry of Agriculture of China,as well as FDA and FAO.

       

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