Fe-Mn-BC(生物炭)填料球三元微电解对稻田镉和啶虫脒复合污染的去除效果及机制研究

    Enhanced Simultaneous Removal of Acetamiprid and Cadmium from Soil and Water in Paddy Fields by Fe-Mn-BC Ternary Micro-electrolysis: Effect and Mechanism

    • 摘要: 通过液相还原法制备了Fe-Mn-BC(生物炭)填料球, 研究了其对镉(Cd)和啶虫脒(Ace)的吸附性能及在室内模拟条件下对稻田Cd和Ace的强化去除效果。结果表明, Fe-Mn-BC微电解填料对Cd和Ace的吸附量分别为6.29和23.62 mg·kg-1, 吸附效率分别是沸石球的2倍和4倍; Fe-Mn-BC填料球对稻田中Cd和Ace的去除效率约为85.00%。Fe-Mn-BC填料球阳极的Fe和Mn在电化学反应过程中释放电子破坏Ace的化学键, 将其分解为小分子物质〔N-(6-氯-3-吡啶)甲基-N-甲基乙酰胺、IM1-4等〕, 进一步降解为水和二氧化碳; Cd则主要通过Fe-Mn-BC填料球吸附和沉淀途径被去除。研究结果可为稻田Cd和Ace复合污染治理提供理论依据和技术参考。

       

      Abstract: In this study, Fe-Mn-BC ternary micro-electrolysis filler was successfully prepared by liquid phase reduction method, and its adsorption to the acetamiprid (Ace) and cadmium (Cd) and its enhanced removal effect on combined pollution of Ace and Cd in paddy fields under laboratory simulation conditions were investigated. The results indicate that the adsorption capacity of Fe-Mn-BC micro-electrolytic filler on Cd and Ace were 6.29 and 23.62 mg·kg-1, which were twice and four times that of the carrier, respectively, and the removal efficiencies of Ace and Cd in constructed wetland (CW) with Fe-Mn-BC micro-electrolysis filler were around 85.00%. The Ace was decomposed into macromolecular substances N-(6-chloro-3-pyridine) methyl-N-methylacetamide, IM1-4, etc. and then degraded to water and carbon dioxide by Fe-Mn-BC micro-electrolysis filler, while Cd was mainly removed through adsorption and precipitation of Fe-Mn-BC ternary micro-electrolysis filler. This study provides theoretical basis and technical reference for Ace and Cd removal from soil and water in paddy fields.

       

    /

    返回文章
    返回