李晴, 谭欣, 周卫宝, 等. 稻壳纤维素基复合水凝胶的制备及其对亚甲基蓝吸附性能的研究[J]. 生态与农村环境学报, 2024, 40(10): 1385-1394. DOI: 10.19741/j.issn.1673-4831.2023.0834
    引用本文: 李晴, 谭欣, 周卫宝, 等. 稻壳纤维素基复合水凝胶的制备及其对亚甲基蓝吸附性能的研究[J]. 生态与农村环境学报, 2024, 40(10): 1385-1394. DOI: 10.19741/j.issn.1673-4831.2023.0834
    LI Qing, TAN Xin, ZHOU Wei-bao, et al. Preparation of Rice Hull Cellulose Based Composite Hydrogel and Its Adsorption Properties for Methylene Blue[J]. Journal of Ecology and Rural Environment, 2024, 40(10): 1385-1394. DOI: 10.19741/j.issn.1673-4831.2023.0834
    Citation: LI Qing, TAN Xin, ZHOU Wei-bao, et al. Preparation of Rice Hull Cellulose Based Composite Hydrogel and Its Adsorption Properties for Methylene Blue[J]. Journal of Ecology and Rural Environment, 2024, 40(10): 1385-1394. DOI: 10.19741/j.issn.1673-4831.2023.0834

    稻壳纤维素基复合水凝胶的制备及其对亚甲基蓝吸附性能的研究

    Preparation of Rice Hull Cellulose Based Composite Hydrogel and Its Adsorption Properties for Methylene Blue

    • 摘要: 染料废水污染对生态系统的可持续性发展构成了严重的威胁。在众多染料废水处理方法中, 吸附法是处理染料废水最简单、最有效的技术之一。笔者以稻壳纤维素为原料, 通过接枝共聚反应, 制备了性能优异的稻壳纤维素基复合水凝胶吸附材料, 并系统研究了水凝胶制备过程中纤维素用量、单体比例、引发剂用量、交联剂用量等因素对水凝胶吸附剂吸附水中亚甲基蓝(MB)的影响。同时, 采用单因素实验结合正交试验的方法对水凝胶吸附剂的制备条件进行了优化, 当m(纤维素)∶m(丙烯酸)∶m(2-丙烯酰氨基-2-甲基丙烷磺酸)∶ m(过硫酸铵)∶m(N, N'-亚甲基双丙烯酰胺)为60∶350∶75∶10∶40时, 水凝胶吸附剂对水中MB的吸附性能最佳。吸附性能测试结果表明, 稻壳纤维素基复合水凝胶最佳的吸附条件为pH值=6.0、温度308 K。吸附过程更符合准一级动力学和Langmuir等温吸附模型, 在最佳的吸附条件下稻壳纤维素基复合水凝胶对水中MB的Langmuir理论最大吸附量可达2 170.0 mg·g-1。此外, 稻壳纤维素基复合水凝胶对MB有较好的循环吸附性能, 当吸附剂投加量为0.5 g·L-1时, 吸附剂在经过5次吸附-脱附后对400 mg·L-1 MB溶液中MB的吸附量仍有658.3 mg·g-1, 去除率保持在82.3%以上。

       

      Abstract: Dye wastewater pollution constitutes a significant global environmental challenge, critically endangering ecosystems. Within the spectrum of treatment methodologies for dye wastewater, the adsorption is recognized for its simplicity and efficacy, distinguishing itself as a paramount technique. In this study, a high-performance composite hydrogel adsorbent based on rice husk cellulose was prepared by utilizing graft copolymerization. The impacts of different factors, including cellulose content, monomer ratio, initiator dosage and crosslinker content, on the adsorption performance for methylene blue (MB) in water were investigated. Meanwhile, the preparation conditions were optimized by univariate and orthogonal tests and the results indicated that the adsorption performance was optimized when the mass ratio of cellulose, acrylic acid (AA), 2-acrylamido-2-methylpropane sulfonic acid (AMPS), ammonium persulfate (APS), and N, N'-methylenebisacrylamide (MBA) was 60∶350∶75∶10∶40. The adsorption performances of the as-prepared hydrogel were optimized when pH = 6.0 and temperature = 308 K. The adsorption process of the adsorbent could be described by the pseudo-first-order kinetic model and Langmuir isotherm adsorption model. Under optimal adsorption conditions, the Langmuir theoretical maximum adsorption capacity of MB reached 2 170.0 mg·g-1. Additionally, the as-prepared hydrogel exhibited outstanding adsorption performance after recycling, and the removal rate of MB in water was 82.3% (when the content of the as-prepared hydrogel was 0.5 g·L-1 and the content of MB in water was 400 mg·L-1, the adsorption capacity was 658.3 mg·g-1) after five adsorption-desorption cycles.

       

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