不同电解质对牛粪生物炭吸附-解吸富里酸的影响

    Effects of Different Electrolytes on Adsorption-desorption of Fulvic Acid onto Dairy Manure Biochar

    • 摘要: 为了探讨牛粪生物炭对富里酸(fulvic acid, FA)吸附-解吸的影响, 减少FA的流失、提高FA的利用率, 采用Langmuir和Freundlic方程、准一级和准二级方程以及颗粒内扩散方程来研究NaCl、Na2SO4和Na3PO4这3种电解质对牛粪生物炭中FA吸附和解吸的影响。结果表明, 牛粪生物炭对FA的等温吸附过程符合Langmuir方程, 动力学方程符合准二级方程; 3种电解质中牛粪生物炭对FA的等温吸附和解吸过程有显著差异, 其吸附量和吸附率大小顺序均为NaCl>Na2SO4>Na3PO4, 解吸量和解吸率的大小顺序均为Na3PO4>Na2SO4>NaCl, MBC吸附强度与解吸强度也反应了这一规律; 3种电解质中牛粪生物炭对FA吸附和解吸动力学过程有显著的差异, 其吸附量和吸附率的大小顺序均为NaCl>Na2SO4>Na3PO4, 解吸量和解吸率的大小顺序均为Na3PO4>Na2SO4>NaCl。颗粒内扩散方程拟合结果发现, 3种电解质中牛粪生物炭对FA的吸附是由表面吸附与颗粒内扩散同步控制。综上, NaCl中牛粪生物炭对FA的吸附效果最好, 有利于增强土壤肥力, 提高有机污染物的吸附能力, 改善生态环境。

       

      Abstract: In order to reduce the loss of fulvic acid and to improve its utilization, the effect of dairy manure biochar on fulvic acid adsorption-desorption was investigated by using indoor experiment. The Langmuir and Freundlich equations, pseudo-first-order model, pseudo-second-order model and intra-particle diffusion equation were used to study the effects of dairy manure biochar on the adsorption and desorption of fulvic acid by the three kinds of electrolytes (NaCl, Na2SO4 and Na3PO4). The results show that the isothermal adsorption process of dairy manure biochar on FA was in accordance with the Langmuir equation, and the kinetic equation was in accordance with the pseudo-second-order equation. It was significantly different for the dairy manure biochar on the isothermal adsorption and desorption processes of FA with the three kinds of electrolytes, the order of adsorption capacity and adsorption rates were NaCl>Na2SO4>Na3PO4, the order of desorption capacity and desorption rates were Na3PO4>Na2SO4>NaCl, the adsorption intensity and desorption intensity of MBC also reacted to this rule. It was significantly different with the three kinds of electrolytes on adsorption and desorption kinetics of FA by dairy manure biochar, and the order of adsorption capacity and adsorption rates were NaCl>Na2SO4>Na3PO4, the order of desorption capacity and desorption rates were Na3PO4>Na2SO4>NaCl. The results from the Intra-particle diffusion equation also showed the simultaneous control of the external diffusion and the diffusion of inter-particle. In summary, NaCl has the strongest effect on the adsorption of FA by the dairy manure biochar, which is beneficial for the enhancement of soil fertility, the improvement of the organic pollutants adsorption capacity, and the improvement of the ecological environment.

       

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